The free software EZbackItUp (http://www.rdcomp.net/ezbackitup/)
will allow you to back up whole folders ignoring open files. You can then copy these to your destination.
I'm not sure why you want to go the RAID0 route. I prefer a single larger hard drive as it will run quieter and cosume less power.
Remember RAID0 is no more secure because you still lose all your stuff if either disc fails, and the chances of one of two discs failing is higher than a single...
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