its not i5 v i7 you need to worry about, its p55 mobo v x58 mobo.
I believe you can put an i5 and i7 into a p55 mobo, but only a i7 into an x58 mobo.
In crossfire, the p55 will only offer x4 on the second lane, while the x58 will offer x16 on both lanes.
If you really want the best from crossfire you will need a x58 mobo and i7 chip, the performance increase over a i5 and p55 mobo with one gfx card will not be enough to warrant the extra money though.
I thought it was x8 (the second lane) for p55?