For overclocking your CPU, you can just make a topic on the CPU or Overclocking forum (I'd just use the CPU forum since there are more viewers there), list your hardware details and people should be able to give you pointers on what settings to use for overclocking your i5 750.
As for overclocking the 5850, I use MSI Afterburner (which can overclock ANY graphic card). However, if your HIS 5850 is a none reference card, then you might not be increase voltage for higher overclock...but I've read some people mentioning Sapphire Trixx can increase voltage for non-reference 5850 as well, don't know if it's truth though.
But remember frame rate won't be the only thing getting bumped...heat/temp, power consumption and energy bill will get bumped too