For occasional use, a 2nd battery is the way to go. If you're going to be doing this regularly, then charging a 2nd battery every day may become quite a chore, especially if you have to charge both in the laptop one after the other.
As an alternative that does use your car battery, I'd suggest starting with a cheapo £5 car battery monitor which will let you keep an eye on the voltage drop, which correlates to the charge level (12.6V = full, 11.8V = empty). I'd expect a midrange 60Ah car battery to run a 65W laptop for approx 5hrs safely but your erm, mileage

may vary. You could then consider uprating your car battery if necessary, because deeply discharging a lead-acid battery will shorten its lifespan. If you don't want to have to keep an eye on a battery meter, checkout
http://www.batterybrain.co.uk/index.html which cuts power before the battery gets too low.
Whatever the case make sure you are using a decent car laptop charger, as using your mains one with an inverter will drain things much faster because they are quite inefficent.
If it's for work and your employer is paying, then the best solution is to simply get a laptop that can run for as long as you need from a single charge. Either an N450 netbook or a more powerful biz grade laptop (e.g. Dell Latitude) with dual simultaneous batteries.