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All 5850's I have seen on utube and on here can do 1000 on the core so if you want to play it safe hit 900 and bump the volts up a bit with afterburner. Memory can be bumped up to 1100 or even 1200 as they are the same spec as the 5870.what is achieveable on these is 800 on the core fine and what memory spd should be easy to get to?
You got to hit apply after clicking on a profile number, and make sure you do what I said to enable overclocks past he overdrive limit.
You should in the settings and enable start with windows and unlock voltage control.
when you game enable your overclock profile, when not gaming switch to default profile to get powerplay back.