Nitrogen-Filled Tyres

No nitrogen is the larger atom. Think you are only considering the atomic number but that is not the only factor. Also the van derr waals forces are weaker in a nitrogen molecule i think so the molecule is bigger. Its been a while since i went down to this level of chemistry so i may get corrected here.

ISTR checking this some time ago and finding out that a nitrogen molecule is about 3% larger than oxygen.
 
Holy thread revivals!
My front tyres are always going soft, no idea why, so I went into my local tyre fitter, and they deflated the tyres, cleaned up the rims, put in new valves, and filled all 4 of my wheels with Nitrogen. It's only been a week so far, and I notice zero difference on the road, but they are still round at the top and bottom, so all is well. Only cost me £10 so i'm happy, well I was after i demanded they take off the nasty green valve caps and put back on nice black ones.
Give it a month and i'll check the pressures again, see how they managed to cope.
 
Absolutely no benefit for the vast majority of people who will pay to use it.

For those who do track their cars heavily it may offer some benefits but in the grand scheme of things it's way, way down the list.
 
They use nitrogen in aircraft tyres as it volume doesnt change with temperature differences(no where near as much as air anyway). I would imagine thats one of the theories behind using it in car tyres so that the pressure remains fairly constant between hot/cold cycles and varying external temperatures. I have also heard it stops corrosion on the insde of the wheel rim due to not carrying moisture the same as conventional air does.
 
Yeah, there's a lot of misinformation in this thread too on nitrogen in car tyres.

basically, as said above, there's little point in using it, even on track day cars, since you'd probably change/refill your tyres before most of the claimed benefits are even relevant.

Both oxygen and nitrogen respond similarly to temperature, so the effect of temperature variation on pressure is marginal, and only important in vehicles where tyres are used over long periods or in extreme conditions. What is much more important is the water content of the air in the tyre, which can expand/contract a lot more and cause problems, especially in planes or similar that fly at minus temperatures. Nitrogen is more convenient to use as a dry gas for applications like this, though a lot of professional air compressors have a trap for excess water in the air they provide - I think!

The tyre compounds are less permeable to nitrogen in general, but the effect only really relevant over years compared to months. You should be checking pressures much more regularly than that. Also, the idea of oxygen corroding tyres inside is not unreasonable, but holds little value for on the road, only really in applications like heavy machinery where tyres are used and remoulded for a long time.

Overall it seems like a waste of time, and a money maker for the places that offer it.

This is a summary of what little information/misinformation I could gather. Feel free to disagree, i'd like to hear what other arguments there are for it too.
 
They use nitrogen in aircraft tyres as it volume doesnt change with temperature differences(no where near as much as air anyway). I would imagine thats one of the theories behind using it in car tyres so that the pressure remains fairly constant between hot/cold cycles and varying external temperatures. I have also heard it stops corrosion on the insde of the wheel rim due to not carrying moisture the same as conventional air does.

yeah used in plane tyres as it doesn't expand like air would the higher you fly
 
The purpose of using nitrogen in the track cars was so you could set the pressures cold and they wouldn't rise with the heat from the tyres. 27.7 psi cold - 27.5 psi in the pitlane straight off the track.

Overkill on regular road/track cars though imho.
 
£10? To inflate your tyres? Lunacy...

Clearly you didn't read my post properly. The £10 included removal and deflation of my two front wheels, breaking the seal, cleaning up the inside rim of the wheel, then inflating all 4 wheels with nitrogen. So when you look at it that way £10 is bloody cheap!
 
The new Nissan GT-R is meant to come with Nitrogen filled tyres.

All it does is completely stabilise the pressure inside the tyre during the tyres heat cycles. Nothing more. It is there fore better in this respect than plain air which also has greater seap properties.

Useless for plain road use
Useless if you take your car to the track once a month
Helpful if you have a pure track car
Helpful if you take your car to the track every week
Helpful if you're an idiot
 
How? It seems to me that both air (about 70% nitrogen, 30ish % oxygen) and pure nitrogen would behave as ideal gasses in this respect and would thusly behave identically for equal molar quantities.
It's 78-21 and 1% other stuff (mainly Argon and a tiny bit of CO2). :)

Holy thread revivals!
My front tyres are always going soft, no idea why, so I went into my local tyre fitter, and they deflated the tyres, cleaned up the rims, put in new valves, and filled all 4 of my wheels with Nitrogen. It's only been a week so far, and I notice zero difference on the road, but they are still round at the top and bottom, so all is well. Only cost me £10 so i'm happy, well I was after i demanded they take off the nasty green valve caps and put back on nice black ones.
Give it a month and i'll check the pressures again, see how they managed to cope.
My inside-rear tyre is like this, I think it's because the alloy rims are corroded (beyond repair), so the air can sneak out. Generally when the tyre gets changed it lasts a week or so before it'll go down, then it needs inflated every two days or so.
 
/edit - So... Nitrogen has bigger molecules than Air/Oxygen, and therefore is more difficult for it to gradually escape from the tyre...

O2 (Oxygen) Moleculer mass = 16

N2 (Nitrogen) Moleculer Mass = 14

So its not a bigger molecule.

/edit: Beaten like a ginger step child on his birthday.

KaHn
 
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Thought the GTR had it and the reason was it doesnt expand like normal air?
(only read first page :p)
 
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O2 (Oxygen) Moleculer mass = 16

N2 (Nitrogen) Moleculer Mass = 14

So its not a bigger molecule.

/edit: Beaten like a ginger step child on his birthday.

KaHn

Just because the atom has a higher mass does not mean the molecule or atom is larger. In fact, nitrogen is larger, because of oxygen's increased electronegativity, though it's by a smaller amount than expected as the strength of the N-N triple bond (which is what makes it inert). This only has a small effect on the permeability of the tyre though.

The pressure regulation is only important in extreme situations. Planes fly at high altitudes with low pressure and low temperature, which puts stress on tyres as the pressure difference is large. However, this would be the case with air in the tyre too, nitrogen is just more predictable and uniform as a single substance. It's just more convenient as a dry gas, which is important as water can freeze at the low temperatures planes fly at, which decreases tyre pressure significantly, and if it lands with very low tyre pressure problems can arise.

The whole point of the ideal gas equation is to model gases. Gases in the real world differ from this for many reasons, so saying it's an ideal gas would not account for pressure differences for different materials. It does not take into account changing molecule interactions over distance or the volume of the molecules themselves, which in high pressure environments, like a tyre, is much more significant than in the air around us.
 
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I was always told that Nitrogen was used because it's expansion rate could be predicted much more accurately than 'air' and it didn't contain moisture in the same way normal compressed air did.
 
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