Here are my bios settings at the moment and pic of cpuz memory and temp settings at 3ghz. I have tried slackening timings on memory, 2 sticks, increasing the vcore on cpu, higher fsb with lower multiplier and nothing seems to get it to load into windows at 3.2ghz.
You should be trying to keep it below 80c really.
The only other settings i touched was to ensure the memory is running within its spec and I increased CPU PLL termination from 1.5 to 1.6. No idea why, just read it ages ago when looking into overclocking the chip.