I use a 2 into 1 cigarette lighter converter in my car no problem. The Satnav uses so little power, less than 1amp at 12V, The max 'normal' load on a cigarette lighter socket is 15-20 amps or so. So thats plenty for a 150watt invertor which should be enough to power most laptops.
I've got a 300W invertor, it can either run in 150W mode using the cigarette lighter or 300W mode but that requires direct connection to the car battery.
Just check what power the Mac needs. If its 150W or less then your onto a winner, Invertor and a 2-1 convertor for your cigarette socket. If the mac needs > 300W, then you'll need to get the invertor wired directly into the car's power systems (properly fused etc)