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I doubt you'd see a difference with QUAD SLI unless you were using a hydra multi-GPU board... 4 card scaling with SLI is inefficent enough that you have masses of headroom physx can use without impacting directly on rendering performance...
bare in mind the NF200 chip usually has x16 lanes into it and then splits that to 2 lots of x16 lanes out... and switches... so its not like having true dual x16 lanes - but for SLI/multi GPU it works great as the NF200 chip can upload data to both cards at the same time and shortcut transactions between the cards... which in theory means you get better gains than normal with SLI tho from my testing it looks like only 5-10% better tops.