Cheers for the help guys, in the end I removed and tested each card individually and then paired them back up which solved my problem... No Idea, but 4k/60-ish fps in Crysis 3 is something to behold!
As promised, now that everything is up and running heres some quick and dirty images of my set up.
(We're moving house within a few months so I haven't put the system on a desk, but the old dining table is working a treat lol!)
Cabling isnt too neat though it's a bit awkward to get it neater, at least it's all black!!
Final Specs:
Corsair 760T Case
Corsair AX1500i
Gigabyte Z97X G1 Gaming Motherboard
Intel i7 4790k
Corsair H105 Cooling Kit
Corsair Vengeance Pro Red 32GB (2400Mhz)
2x Powercolor R9 295x2
4x 1TB Samsung 840 Evo SSD (RAID 0)
Benq XL2720Z 27* 1080p Gaming monitor (Left)
Asus PQ321Q 32" 4k Monitor (Right)
Bose Companion 5 (temporary speaker set-up till move)
Corsair K70 Vengeance Keyboard
Corsair M65 Laser Mouse
Steelseries H Wireless headset