Overclocking using the multiplier on Phenom chips is the only practical way to play with them.
Forget everything you know if you've used an Intel chip as - whilst identical in aim - the procedure is vastly more complicated.
The Black Edition - being multiplier-unlocked - can be overclocked just by setting the multiplier higher. Basically do this until the chip becomes unstable (Orthos for at least 8hrs, 3Dmark06 for 4hrs. encode a full-length movie into DIVX/MKV and then SuperPi/PiFast to 32m decimal places... all followed by 24hrs of Toast - this is what I would consider a full stability test). If the chip passes each overclock with such settings, you can be reasonably sure it doesn't need additional voltage to go higher.
The thing with Phenom is better performance is available by tweaking the Northbridge clockspeed (no, not NyperTransport). Increasing the northbridge frequency has a direct impact on L3 cache latency which is a serious stumbling block for the chip.
If you decide you want to play with the Northbridge frequency, make sure you increase it so that its final
total value (i.e. once appropriate multipliers have been added accordingly) is higher than the Hypertransport value.
You will not get any stability at any voltage if you do not follow this principle. This is why so many benchmark sites had problems with Phenom overclocking before the Black Edition came about.
Another thing to remember is that Northbridge voltage can be adjusted independently to the CPU and RAM voltages. By the same token, dont give it too much juice (put a limit on 1.45V for pretty much all CPU-bound things if on standard cooling) or it will kill the chip.
Just take your time, head over to
http://www.xtremesystems.org/forums/forumdisplay.php?f=58 (but READ the threads; don't just go and ask how to overclock your system) and enjoy.