We get complaints from people when emails from "Name of Manager" <
[email protected]> asking for bank transfers to be made to certain accounts get through the spam filter - it's very difficult to explain that that's not really a spam message. The only way to deal with it is either to have content policies that bin anything with a bank account number in, at which point you cripple the ability of your accounts team to get work done, or you have a rule that marks all external email in an obnoxious way. User education is probably the best way to tackle this stuff.