UHArc will give the best compression results, closely followed by WinRar in solid mode. TBH though, compressing a single file isn't going to yield you much in the way of benifits by the simple way the compression process works, never mind the fact these are videos.
You'd be far better rencoding it in a decent high-compression codec
Winrar is also very good however its only a 30 day trial. If you are looking for maximum compression, I have found 7zip to be slightly better at reducing file size.
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