On the assumption that the pump is reporting correctly (and there is no reason to believe otherwise) that's odd.
From those screen shots, it looks like the heat isn't being dissipated from the radiator as both CPU and the pump temps are very high.
If you click pump in Corsair link, you can set it to Performance mode which pushes the liquid around a bit quicker.
I don't think that is the problem per se, but may give you an extra minute or two within Windows to troubleshoot.
I would personally perform a visual inspection of your H100 around the pump to ensure there has been no leakage. I would also inspect your radiator to see if it is heavily clogged with dust. Also ensure your fans are running as expected (visually can be tricky, but I mean along the lines that they are spinning at a decent pace).
If all above are ok, it may be that there is air within your loop. I read an article a while back which suggested that over longer periods of time, some Corsair AIO coolers will "lose" some of it's liquid and air pockets can appear. I'll see if I can find it.
Lastly, there maybe crud in the loop preventing a decent water flow. Not something that you could do to prevent, but again something I read some time ago whilst researching the Corsair AIO coolers for my rig.
If it's either of the last two, you could be adventurous and try and refill/disassemble to fix... But I would personally buy a new AIO.