A hair drier would probably soften the tubing a bit, enabling you to wiggle it off by hand
If that fails, you could VERY CAREFULLY use a needle nose pliers to work the warmed tubing back and forth over the connector.
Have you tried twisting it? To break the 'seal' so to speak, not that it has a seal.
I'm with Diddums on this. The tubing has likely gone hard and should be replaced as it will never seal properly again. Chances are that it will be a much easier job replacing the tubing as well.
I wouldn't normally advise it but a little jubilee clip (cabletie4lyfe) might do the trick. Doesn't need to be on very tight, just to enough to add a little bit extra grip. Worth keeping one in the car as temp fix if it pops off whilst driving.Well I've replaced it and now will monitor for leaks, I could replace the tubing but its a much harder job the way its routed from the pump to the wiper blade