A 2000 xantia with 75k?
Doesnt seem likely. Still it is also an auto, which were an unusual choice as its not a very good box iirc. Also you dont say whether its petrol or diesel?
With re: to the knocking noise, on the whole the xantia has much the same basic suspension setup as a conventional car. However, of course, the springs and dampers are replaced with hydraulics.
So you need to do all the usual checks, ball joints, various arms, wheelbearings can be one if its a noise on the move etc etc. But then you also have the strut top ( the bit under the bonnet with the hydraulic sphere sticking out of it), make sure the top of that isnt corroded through (bit of rust is to be expected).
What is the suspension like as a whole? It should rise quickly to normal ride height once started, without any groaning. It should fall relatively smoothly and evenly when ride height is put to minimum and then rise after about 30 seconds (and the STOP light comes on) if you then put it staright into its highest setting. Also, with it at normal, press firmly on each corner of the car, it should give easily but then after a few seconds resist you and physically push you upwards. With the car at idle, there should be an audible click at the front of the engine bay every 1-2 minutes (ideally 2). If its more rapid than that then the accumulator sphere is on its way out. Not a big or expensive job in itself but it can have a detrimental effect to the whole hydraulic system until it is replaced.
Open up the LHM reservoir (cap to the back right of the engine bay) and just dip your finger into the fluid. It should be clear green or possibly yellow, though really it should be green. If its a dark muddy green or yellow then its LHM hasnt been changed at standard intervals (36k iirc) meaning the hydraulic system as a whole hasnt be maintained. In which case i'd walk away.