Cold Boot Problems. PSU?

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I've just put an Opteron 165 in my PC and I'm getting some cold boot issues when overclocking. I had it running at 2.6Ghz for a week or so and it was flawless, but I've started to have problems. When I boot from cold, it can take up to 10+ times to start it on a bad day. Once it's up and running it seems fine; I can play games and do other intensive activities without errors or crashing, orthos ran fine etc.

Anyway, I was starting to think it was the mobo or the CPU, but it can't really be either. I've had this mobo up past 300HTT without a problem (I ran my old 3200 @ 8*300 for ages) and the CPU is obviously fine if it can sustain a week at 2.6Ghz with me thrashing it using BF2 a lot (so it's a fair assumption that if it can maintain load in windows it can boot at the first time of asking). Anyway, I knocked everything back to stock and it boots first time, every time. So, what could the problem be? Could it be a PSU issue or something like that? I rarely trust the voltage readouts in various programs, but mine are looking rather skewed these days (3.07v for the 3.3v and 12.45v for the 12v). Also, I've noticed that when I crank up the vcore, it barely seems to budge in the readouts. I'm not sure whether that's my MSI board undervolting though -- it's a known problem. When I set my vcore to 1.4725 the readout is more like 1.37.

The only other weird thing is that sometimes my sound in games will start going a touch loopy -- it almost sounds like someone blowing a dog whistle. Again, this only started happening recently and it's intermittent. It happens maybe a couple of times per week and, generally, restarting the game fixes it.

Specs:

Fortron Source 400W PSU (3 years old) -- spec: http://global.aopen.com.tw/products/power/FSP400-60PN(PF).htm
Opteron 165 & Retail cooling
MSI K8N Neo2 Platinum with Sideeffect's modded BIOS (1.C final)
XFX 6800GT @ Ultra
SATA & IDE HDDs
CD-RW & DVD-RW
Sound Blaster Audigy

Any ideas? Cheers.
 
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Anyone? Is there a way to test a PSU if you don't have any decent quality spares? I don't want to go fork out £50-60 on a new PSU if I don't have to. Even worse, I just ordered the Antec Nine Hundred gamer case a few days ago and it doesn't come with a PSU. I could've just ordered a different Antec case that comes with a 430W PSU >_<
 
Do you need that second optical drive? All those Hard drives?

It is likely you are pushing the limites of your PSU - hence the cold boot stuff. However you can limit that by dialling back the number of loads you are putting on the PSU.

Do a google search for PSU calculator and see how over budget you are - and what needs to be switched off temporarily.
 
I have too much time on my hands - assuming no Capacitor Aging your budget is about 380 Watts.

Assuming just 20% capacitor aging which is lowballing a 3 year old PSU - you are looking at 420. Age is killing your machine.*

http://extreme.outervision.com/PSUEngine

*Electrolytic capacitor aging. When used heavily or over an extended period of time (1+ years) a power supply will slowly lose some of its initial wattage capacity.
 
Just to top this and post the resolution: I bought a Coolermaster iGreen 600W and my PC is now happily running at 2.6Ghz again without any startup issues. So yes, it was definitely the PSU that had deteriorated.

Btw this is the noisiest PSU I've ever owned. How on earth they managed to put such a loud fan on a supremely efficient (85%) PSU I have no idea. Both this and my previous PSU both have 120mm fans, yet this one is noticeably louder. My old one wasn't audible above the rest of my case fans; this one... I can hear.
 
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