Actually running a single loop gives better temperatures than two loops. Though two loops with two reservoirs would have more coolant to 'carry' the heat, after a few minutes, the water temperature will reach equilibrium and the effects of the difference in coolant volume is negligible compared to the advantage a single loop has:
A single loop with multiple components has the benefit of more effectively sharing out your radiator cooling potential more efficiently (in a single loop no components that produce heat are isolated from radiators). Different components output different amounts of heat but this isn't an issue in single loop, as all the heat producing components are in the same loop as all the radiators. In two loops you may have one component in one loop requiring slightly more cooling than the other. No matter how you divide the radiators between loops, one component will be cooler and the other warmer than if you were to have a single loop.
Also components come under load at different times and therefore need different amounts of cooling depending on their loads relative to eachother, having a single loop would equalize the temperature between components better, while two loops would limit the overhead of one component when the other is relatively idle.
If both components are in acceptable temperature ranges (which is our aim), having one of them any cooler at the expensive of the other being warmer is not only of no benefit but can be a disadvantage when you want to push them for part specific benchmarks and you need that extra overhead on a single component, eg. having GPUs on a separate 360 loop to a CPU in a 240 loop would limit you more thermally on a CPU only benchmark than a single loop, which could use the extra radiator cooling power when the GPUs are idle.
Going by theory, dual loops would only match the temps of single loops if components and radiators were distributed so the heat output of components match the amount of cooling distributed between the loops AND the loads stayed balanced. All other situations single loops would provide better temps and higher reliability with two pumps.