If the garage that did the MOT can't test the various emission systems due to not having any diagnostic equipment suitable for your car, then you're better off taking it somewhere that does. They may start replacing parts they 'think' are causing it otherwise, or possibly replace your catalytic converter/lambda sensor(s) without determining if the engine is running correctly (overly rich fuel mixture would quickly ruin a new cat).
Ask them for a printout of the emissions results, that way it's possible for either you or another garage to get a rough idea of where the problem lies.