My friend is getting this error also on his new build from the weekend. F5f bios. Then I found this on a reddit post.
post from a gigabyte staff member on their US forums
He said the following about code 66: "Not sure if it needs to be fixed, as its working as intended. The board, when cold, will retrain the memory on boot. It will go from tightest -> relaxed until something sticks. If the tightest timing works then you should see A0 (boot successful). If it fails even once it will show 66 (atleast one failed boot) . On a soft reboot it already has the timings trained, thus it clears the code and shows A0. The only way to fix this would be to boot successfully on tightest timings. We could fix this by creating a less aggressive profile, however those who are booting with the most aggressive profile would lose performance. That being said I'll check with our BIOS guys but I believe its working as intended."
its at this moment I realize this is a gaming 7 thread. my friends is a gaming 5... oops