Your temps looks good, provided that your CPU is overclocked.
I think the reason why your H100i fan rpm is not revving up, is because you have those fans under H100i/coolant temp group and not CPU temp group. By default, both fans will be under H100i/coolant temp where the fan curve you set will vary on the coolant temp and not CPU temp. Technically, we do recommend it that way. Coolant is the agent that dissipate heat from the CPU, so it would only make sense if you have the fan curve based on the coolant temp rather than the CPU temp. Plus, CPU temp will fluctuate more frequent as oppose to the coolant temp which will be more linear and steady.