Maximum recommended vcore for Haswell is 1.35 and I wouldn't have mine anywhere near there on air. If you look at advanced voltage settings in BIOS, vcore will be set at auto but you will see what the BIOS has it set at (number next to auto).
Also, your CPU shouldn't be at 4.2ghz stock frequency.
Yeah I know it shouldnt be that at stock, the mobo just booted it at that speed on first power up (along with alarmingly high voltage). The vcore in the bios showed as slightly less than the 1.428 that HW Monitor reported (think bios claimed it was setting around 1.35 on auto)
I've set it to manual now (as the auto setting was obviously too high).
Best I have got so far is with VCore of 1.31, VRin of 1.9 and Ring of 1.2 with cpu at 4.6. Last about 5-10 mins in prime 95 before a blue screen, for first round of tests it peaks at around 75C, but when it starts the second round of tests temps shoot up, peaking at 97C.
CPU @ 4.5 with vcore of 1.295, Vrin of 1.9 and ring of 1.2 seemed stable, but again temps shot up in second phase of prime 95, peaking at high 90's.
This isn't on air though this is a OcUK 480 water cooled rad kit in use, disturbing that the temps are that high.