Well the FAQ or Corsair PSU Support section does have a bit about 'I hit my power button but the PC doesn't come on'
It recommends hooking up just one fan and trying the green to black pin short on the 24pin connector so i'll give that a whirl.
Good thing I have a seven year warranty on the AX series PSU!
edit:
I think I know what it was.
Had back panel off to install an old HDD.
The drain tube bung/stopper was up against the rear of the CPU!
It may have been shorting there, miracle my PC works at all!
Repositioned it and it booted on first power button press
PSU is fine it would seem thank goodness
edit edit:
whats weird is that although power-on is now solved, PC has reverted back to no signal out of primary GPU until PC has been on 5 mins then reset.
I read it was to do with PCI-E capacitors not charging properly on Asus Mobos and not properly activating the primary display GPU in SLI.
So now the short is gone the PC has gone back to its old annoying habit!
Think I prefer the shorted-out version!
Just for info of this thread determined that it was the power monitor plug that was causing the problem (the PSU was plugged into this).
I think it has an internal battery and it was running low, eventually the display was fading and the unit beeping at me.
Took the plug out and run PSU directly into socket and now boots evertime
edit edit edit:
For further reference it was not the power meter plug at all.
Going to have to hook up old PSU to see if that's the issue
Moar for the archives:
Put in my old HX620 Corsair PSU and it worked first time. Got RMA going through with corsair now.
Second time I have RMA'd their flagship range PSU!