Those look like Sanyo OS-CON caps which are computer grade caps which use some sort of organic compound I think, which is supposed to be more durable than a normal electrolyte cap.
They should not hiss however...
Is it actually possible for them to hiss? I mean, I didn't pinpoint it to the capacitors. It could have been the PSU for all I know. I wasn't really thinking about it much at the time so I didn't try to listen to exactly where it was coming from. I'm half tempted to try it again and try to listen to where it is coming from, but I fear I'll cause further damage if it is infact the capacitors

Currently though, the system is very fast and completely stable at 3.8 with load temps not exceeding 60 (usually don't pass 50 when playing games). I'll be very happy leaving it at this freq, I just want to make sure my motherboard isn't a ticking time bomb. I can't really relax until I know for sure.
EDIT: I might email Gigabyte about it. Does anyone have an Email address for gigabyte where I could ask this sort of question?