That's easy enough to do using Robocopy and Task Scheduler. I have a batch file that runs every night to mirror my data drive to another inside the PC and to my NAS. Let me know if you'd like the details.
Robocopy is a command line program and needs a lot of parameters to make it work. It is possible to make it copy a whole drive in one go but it can get hung up on system folders like the recycle bin so I have a line in the batch file for each top-level folder. This a sample line from one of my batch files:
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