The goal of the header designer is to tune the travel of the negative pressure pulse of one cylinder so it hits the port of the next exhaust event of a different cylinder. How well this is accomplished determines to a large degree the power curve of your engine.
Building a good exhaust header and system is quite an artful application of science. It's all about synchronizing a sound wave and a rapidly cooling, and therefore shrinking and slowing, exhaust gas pulse traveling down the tube with another cylinder and its valve timing events. Keep in mind that when the exhaust valve cracks open, a sound wave punches out of the exhaust port at the speed of sound, approximately 18,500 inches per second, followed by the exhaust gas slug at about 3,600 inches per second. If the design is correct, when the high-pressure part of the sound wave passes through the collector, it is creating a low-pressure condition that reaches back through the other tubes and "pulls" the next exhaust pulse out of the cylinder, or at least offers less resistance than otherwise to the exiting gases.