mklink /D "D:\Games\Titanfall" "F:\Titanfall"
There is a program called steam mover, which apparently also works with Origin games!
I have never used it, so can't comment on its user friendliness etc however.
No need simple method
Close Origin, Copy TitanFall folder to SSD and Rename TitanFall.BK now open Origin and change Download to C: and start Download wait 1% close Origin
Now go back into C: Origin games and delete your new folder and re-name other back to normal. Open Origin and now the Download will jump to 100% and continue to install.
Simple
Steam is also very easy just copy and paste with that.
mklink /D "D:\Games\Origin Games\Titanfall" "C:\Program Files (x86)\Origin\Origin Games\Titanfall"
To reverse it, simply delete the D:\Games\Origin Games\Titanfall directory (this just deletes the link, not the contents, but if you don't trust it then copy the directory over to your D drive first) and move the Titanfall directory back from your C drive to D:\Games\Origin Games\Titanfall.