i have got same motherboard mate, its bit more fiddly getting overclocking but i Oc my i5 2500k to 4.4ghz at 1.3V.
Google " i5 2500k asus oc" lot of people sharing there views with asus + i5 2500k + overclocking
You can not i repeat can not manually set Vcore, all you can do is adjust Max turbo voltage (the extra voltage thats pulled through the cpu when you go into turbo mode)
increasing this Max turbo voltage by +0.08 to get stability
My settings are
44 Multiplier(on each core) and Max turbo voltage 0.2
you can only see the "max turbo voltage" if you go into the cpu setting option in the advanced bios settings
I wish there was more info about this motherboard, my initial research before buying this board came up with nothing.
Kind of weird Asus selling a board for unlocked cpu (i5 2500k) but not letting you adjust cpu voltage directly, really weird.
Its like they dont want you to overclock.. with a baord designed to overclock lol!
I always recommend now NOT to get p8p67-m board, so much less hassle going for something from gigabyte/msi etc. or going for pro version (p8p67 pro)
you can overclock cpu we just have to jump through a few more hoops to get it done, and have a lot less tweaking options.
i5
[email protected] 4.4ghz is still considerable boost in performance
PS: we have like exactly same pc lol except i went with haf 912 case ^.^
Good luck!