Soldato
Hi wingman 
After some experimatation this is what I found gives the best results:
After tinting both mating surfaces, a pea-sized blob, a small garden pea rather than a big marrowfat one, applied to the centre of the cpu. Using the TIM syringe I then gently spread it into a little square blob about 15mm square. When attaching the heatsink I too found the tendancy for it to begin sliding even if it was very level, I lower it into position then rotate about 20 degrees in either direction before screwing down. When screwing down I do both sides up hand tight then alternate with a quarter turn on either side to ensure even spreading of the TIM as the heatsink pressure on the cpu is increased.
Tinting the surfaces prior to the actual TIM application gave me a noticable temperature drop, this is something I reckon many people overlook as I don't read about it much on here & you can clearly see that the imperfections have been filled, no matter how hard you try to scrape it all back off some remains emedded.
Regarding the drying out of TIM I also found this with MX-2:
After about 2 weeks I began getting a steady rise in load temps, I suspect the MX series of thermal pastes gives good results out of the box but degrades as it cures, wheras AS5 improves as it cures & since I went back to it I've had excellent results:
http://forums.overclockers.co.uk/showthread.php?p=18124491&highlight=temp+creep#post18124491

After some experimatation this is what I found gives the best results:
After tinting both mating surfaces, a pea-sized blob, a small garden pea rather than a big marrowfat one, applied to the centre of the cpu. Using the TIM syringe I then gently spread it into a little square blob about 15mm square. When attaching the heatsink I too found the tendancy for it to begin sliding even if it was very level, I lower it into position then rotate about 20 degrees in either direction before screwing down. When screwing down I do both sides up hand tight then alternate with a quarter turn on either side to ensure even spreading of the TIM as the heatsink pressure on the cpu is increased.
Tinting the surfaces prior to the actual TIM application gave me a noticable temperature drop, this is something I reckon many people overlook as I don't read about it much on here & you can clearly see that the imperfections have been filled, no matter how hard you try to scrape it all back off some remains emedded.
Regarding the drying out of TIM I also found this with MX-2:
After about 2 weeks I began getting a steady rise in load temps, I suspect the MX series of thermal pastes gives good results out of the box but degrades as it cures, wheras AS5 improves as it cures & since I went back to it I've had excellent results:
http://forums.overclockers.co.uk/showthread.php?p=18124491&highlight=temp+creep#post18124491
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with rice grain method compared to the results with horizontal line method which I posted previously.
plus it requires modestly low load voltage at 3.4Ghz