Hi
It is possible to measure the total load pulled from your mains socket in tersm of whats/amps by buying a small meter for about £30 from most major electronics stores, they simply plug between the mains plug and the wall socket. The only way I know of to test the amps being pulled from a specific rail would be to attach a meter where the rails enter the PSU, however this would be difficult as I dont know how you can find all the 'rails' without knowing the PSU's full circuits.
May I ask why you want to do this?
Mike