The Corsair CX400W is more than fine for a Core2Duo system plus that card. Only have to start concern about whether it is enough when using a highly overclocked Quad with it.
If there's anything to worry about, it should be whether or not the E6300 will be bottlenecking the cards. Is your E6300 the 1.86GHz version, or the 2.80GHz version? If it is the 1.86GHz one, I'd look into upgrading the CPU as well. Even if it was the 2.80GHz version, if you are not overclocking the CPU, you'd probably better off grab a GTX260 216 2nd hand for £60 than spending than spending as much as £125/£170 on getting the GTX460 768MB/1GB, as the dual-core at only 2.80GHz WILL bottleneck the mid-range or above cards.