The only really significant difference between most single and dual rail PSU's is that dual rails have a 20A/240VA current limiter on each rail and maybe a voltage clipping zener diode. It's misleading, in 99% of cases there's only a single 12v source. It's the total combined wattage that matters. A crossfire system may be able to reach 20A. Most of the OCL's are set higher than 20A, but not all, so some trip out and the PSU shuts down.
Look for the total combined wattage for the 12v outputs. Don't just add the two rails together, you may not be getting as much as you think you are!