there's no "better" and any measurable difference in temps would be more than made up for in natural fluctuation in the ambient temp of the air getting to your rad, I'm almost completely convinced of that.
The only concern is the tightness of bends and even that doesn't have a flat answer on tubing size, its often as much to do with the quality of tubing.
I remember after seeing all the hype about tygon I got some off the bay, 1/2" but it turned out to be the thin wall stuff which is complete toilet, the thick walled, much more expensive is the real top end.
However masterkleer 7/16 tubing seems to be a good compromise, likewise I am using XSPC 7/16 at the mo and it bends very well.
Really there is no better, just whatever you fancy using. Unless you're using a tiny case good planning will avoid any tight bends anyway.
And don't ask about loop order either, that makes next to no difference either

just make sure your res is before your pump as that makes it all a lot easier to fill.