Did you put them into the same channel DIMM slots accidentally? Check manual to make sure you have right slots in use.
:: edit ::
Bah, misread you having 1 pair, not 2 pairs. My bad.
Single Ranked in that case is about the DIMM Modules themselves, as they could be Dual Ranked as well. Shouldn't be anything strange there.
:: further edit for clarification ::
DIMM Modules can be Single or Dual Ranked (which is what you're reading about your DIMM right now. This is different from Single or Dual "Channel" which is what the memory channel is running at. So you can have (in theory) Dual "Channel" for Memory that is made up of Dual "Rank" DIMMS (so x4 in this motherboards case). Or you could have Dual "Channel" for Memory that is made up of Single "Rank" DIMMs too. So long as they are all seen by the system, there's nothing to be concerned about there.