Elite Dangerous, but I think they stopped VR support a while back. Star Wars Squadrons campaign supports VR too.
all in vehicle parts of elite are still in full VR (I have only ever played it in VR other than some very simple stuff on my steam deck watching telly)
the on foot stuff I also still play in VR but it plays as a 2D giant 2D screen . not brilliant but playable.
over all elite is a must have game for any PCVR player imo unless space has no interest to you.
I agree squadrons is worth a look (who didn't dream of flying an X wing or tie fighter as a kid?)
there are loads of games that work ok seated with a pad many are free vr.mods.
mother mod for alien isolation is a must experience tho it is a flawed vr.implementatiom
Doom 3 BFG has a superb VR mod that works on a pad if you want.
some of the early oculus titles were controller based and seated (the rift DK1 l, DK2 and even CV1 at launch relied on a pad and officially we're seated experiences.
try edge of nowhere and Lucy's tale.
Hell Blade is superb in VR the sound really makes it.
yuka laylee has a superb VR mod as well