It drives me nuts, my current company gets a lot of these spoofed e-mails from the CEO etc.. I believe Linkedin to be the "data source"
On my personal domain, I've got all SPF, DKIM added & use digitally signed mail (£30 for a certificate) & will be implementing a similar setup and my current company
In the interim I've got Exclaimer adding a header ("This e-mail has been sent from outside xxxxxx Check that it is genuine") to each e-mail that comes from external source
I used to work for a fairly large company, one day the performance of our exchange server tanked, upon investigating it turned out that our product development team was throwing 500k customer transactional e-mails at it. We soon ended up on a few mail blacklists.. It took me best part of two solid days building a dedicated mass e-mail platform & getting the SPF, DKIM records in place & liasing with various different mail providers get our servers whitelisted