To achieve the best finish it's all preperations!
First of, i'd get yourself some fine wet and dry sand paper, sand the case down to bare plastic, apply some plastic primer, make sure you apply it evenly, you could wet and dry sand it again and apply more plastic primer, depends on how good you want your finish to be.
Obviously when all the prep is done, apply your matt black spray paint, if you want to keep the look of th Matt black, then you'd need a couple coats of clear laquer.
Hope this helps.
Andy`