Thermal paste after it has frozen?

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Just a short question I've been wondering:

Once a thermal paste gets frozen, does it lose its thermal characteristics?

More detailed description:
At some point I inadvertently placed my Noctua NH-U12F's thermal paste syringe on the outdoors storage room (must have been there for about a year or two), and the temperature can go as low as -30 celsius in the winter.

I was thinking that considering it's probably a highly synthetic compound, it might not be affected (or maybe -30 C isn't even enough to freeze it?). But also precisely because it's a compound, I fear that it might have frozen first only partially (higher melting-point alloys), and afterwards the rest (lower melting point). And once it thaws out, it might not melt back to its original "structure"/"mix".

From an outside inspection, it looks normal, there's no visible un-evenness, air/liquid bubbles or anything like that. It also spreads like it used to, I think. If an outside person saw it, he wouldn't be able to tell that it's been frozen at some point. But I just don't want it to start boiling if I put it on the heatsink.

Furthermore, it was bought in 2006, so a follow-up question would be: does the thermal paste lose its characteristics over time? There is a cap on the syringe, so it doesn't come into contact with air, at least. But now it's a 9 years old thermal paste, and if I end up using it on the new rig, as well, it will probably stay untouched for ~5 years more.

So, as I'm building a new rig atm, I was now wondering whether I would have to invest in an extra thermal paste syringe, as well? Or is it perfectly safe to still use it?
 
Overclockers that use LN2 use paste and dont suffer any performance issues.

http://www.noctua.at/main.php?show=productview&products_id=13&lng=en&set=1

That is your paste?

Volume 1.4ml (for at least 15 applications)
Specific mavity 2,49 g/cm³
Colour grey
Recommended storage time (before use) up to 2 years
Recommended usage time (on the CPU) up to 3 years
Peak operating temperature -50°C to +110°C
Recommended operating temperature -40°C to +90°C
 
Mine came in the NH-U12F package. It's a generic (no labels) clear plastic syringe with white paste and a small blue cap, like in here:
http://www.dvhardware.net/reviews/noctua_nh_u12f/2.jpg
(from a DV Hardware review of the NH-U12F)

The NT-H1 wasn't yet even available when I bought my unit. But yes, there's a high chance that it's actually the same stuff (or similar in characteristics) that they use in that one, as well. It's probably not BETTER than the NT-H1, at least.

Hmm, from the looks of it, LN2 is a liquid nitrogen solution? If that is OK without any special thermal pastes, then I think I should be OK with regards to the temperature. The recommended storage time is a little discouraging, though. Seems like I'll have to invest in a new thermal paste, then.

Thanks for the input. :)
 
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