I have just run the mafia 2 benchmark all maxed at 1920x1200 with my gigabyte hd 7950 oc and got an avarage framerate of 19.8 , card is clocking up acording to gpuz . I cant think whats wrong as most benchmarks say it should be over 100 . ???
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Well that sounds reasonable, I take it you haven't overclocked it.
Try reinstalling your drivers a d making sure physx is disabled in the mafia 2 settings.