CISCO now is THE main qualification to get now, a lot of IT companies would say that networking is where the money is right now. I was offered to do that but i decided not to due to the fact that the education system in UK is dreadful imo and the course was 2 years and although it was free, i did not like aspect of being around 16/17 year old kids for 2 years lol
Anyhow im going off topic, i think CISCO would be good to have even if your not going down the networking route, because general IT jobs uses networks and having basic knowledge is always a plus. If your lucky and work for company who trains their workers to gain this then this would be known as a charlie sheen "winning!" but if your looking to do this outside of work, expect to pay a lot of money
Microsoft certification is also a must but yet again the cost of them are huge.
Gain experience by getting into apprenticeships, better if your between 16-24 but if your older then you would need to fund yourself in this. But if your working at the same time then i say its worth going for as apprenticeship scheme has been improved in UK (******* finally) and the government is funding them and not the employer. You may also be lucky to land a placement and actually gain employment with them if you complete your course.
I might of rambled on abit but to sum up, CISCO is a must for networking, Microsoft certification is also a must they are the top 2 to gain, but to gain experience apprentice courses are the best thing to go for right now.