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q9450 if u can afford it if not q6600
Hmm.. I remember people on the ASUS forums having trouble with 45nm CPUs on the P5W DH back when I used to own one.
lol sorry.
The cache will make a nice difference but it's not as significant as you think. Also you can gain a lot of performance by setting the FSB to 400mhz which pretty much any modern board will do and the CPU will most likely do it without even touching voltages.
http://www.techarp.com/x264_Benchmark/hd//results-2.htm
You can see results there...obviously lower is better, the ones in red are overclocked