>>> That way.
It's pretty simple, get the location of the sunrise, location of the sunset, get the midpoint between them then you know that is south and the other direction is north.
(I know some astronomer is going to come in with some sort of earth wobble theory)
EDIT:
Another way, if you just know the time of the sunrise and sunset, get the midpoint in time between them then point the hour hand of your watch at the sun, halfway between the mid-time and the hour hand will be south, opposite direction is north.