BBC2 has Heroes. You can get 24 and ER on DVD too
BBC natural history, Top Gear, QI, Live at the Apollo, Mock the Week, Have I Got News for You the list goes on.
Aye

Casualty, Spooks, EastEnders (yes I know), Panorama, Hustle, University Challenge, Eggheads, loads of new UK produced Children's content, Antiques Roadshow, Songs of Praise, Crime watch, Life on Mars (finished now I know but a good example as ITV and C4 were both offered it pre-production), the list goes on and on, and have a huge amount of variety over the average week (or even just over most days).
Not to forget the news that was being complained about, something ITV, C4 and 5 have been trying hard to get rid of the obligation to show as it's not profitable

(do C4/5 even do any local TV news? I know ITV is trying to kill it off).
Or the likes of Primeval, which was going to be dumped by ITV until the BBC's commercial arm (Worldwide) offered to co-fund it in return for distribution rights (a classic example of the BBC looking at more than just how much something might be worth on it's initial showing...unlike X-Factor which will have great audiences the one time, a reasonable drama/series will likely get good/reasonable audiences and even DVD sales over time).
I note Energises one suggestion for C4 is now finished
One of the biggest reasons for me for the Licence Fee, is that it actually helps bring money into the UK (with the content that can be resold abraod), and provides content made in the UK, supporting a lot of smaller UK companies who can produce great content when given the chance.
If we did have at least one decent PSB who didn't have to worry about just the quarterly profits, I suspect we'd lose most of the UK production facilities and expertise, it says something to me that ITV have chosen the guy who has butchered the Public Service commitments of RM to be it's new head (almost as much as how little Sky actually produces on it's own, other than where they have a virtual monopoly and can't buy it in, such as Sports coverage).