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daft question but why would you want to overclock this card....
It plays everything maxed out at stock speeds ......
I use MSI Afterburner
The thing you should know about overclocking 5850 that's not made by MSI using MSI afterburner without flashing the GPU's bios, is that you loose powerplay (ie no power-saving mode, your card will run at the speed you set in afterburner in 3D and 2D, which means higher temps and shorter life span). I only use Afterburner when playing games, so in web-browsing or general 2D stuff I still got CCC's powerplay.