D5 will cope with the added rad, you may need to use a slightly higher setting, 3 or 4 maybe.
When you fill the loop for the first time, you fill from the res and the next component has to be the pump so it is primed. I filled my res up and using a psu bridging plug (you can do the paper clip trick but for £1 seemed better to just buy the plug) turn on the pump so that the water from the res goes around the loop, turn it off before the res empties. Repeat this until water comes back around the loop and the res fills from the water already in the loop. The pump may make gargling noises as air bubbles pass through it, this noise will dissapear once all the air is out.
At this point i let the loop run for a few minutes to allow the water to push the easy to get to air out of the loop, turning it off as soon as the water in the res dropps and got close to the bottom. Then top up the res again and turn on and allow to run, keeping an eye on the water level in the res and again turn off if it gets low and top up.
You'll notice the water balances after a while, the res will be full of tiny bubbles that will go over time. Now it's time to get the air out thats stuck in the rad, corners of blocks and any high points in the tubing. Make sure your res has all the caps on and there are no open inlets/outlets in the loop. Depending on how your loop is set up you'll chase the bubbles out differently but the principle is the same.
Turn on the pump and move the system so that the rad is upright (fittings at the top) making sure the air in res does not go out of outlet. This will bring air to the top of the rad and move it to the next component, the cpu block. Again move the system so the outlet on the cpu block is the highest point and the air will move round to the next component. Repeat on each subsequent component until all the air reaches the res. Top up the res at any point that it gets too low that the pump would not be primed.
Let the system run for what you feel is long enough to leak test (8-24hours generally) before you put the rest of the pc components in. Over this time some more air may work its way out and the system will become quieter and quieter until it's silent. Hope that makes sense
