I have met a few people who deal in rural WiFi installations over the past few years. So they mainly install setups in places where good broadband isn't available neither is any cabling.
In those cases, using small building mounted masts, and well placed antennae, as well as some boosters (last guy i met had some not technically legal in the UK 1w boosters for example) a 15dB patch aerial could transmit about 3km with line of sight. Using this, he would create a patchwork that let him share a single connection to a few rural houses that didn't even have phonelines.
Now i'm sure you could in theory do this on a larger scale, but the problem you have is that because WiFi uses radio waves, without massively boosting the signal it's tough to get it to travel over massive distances (hence mobile phones use microwaves I would guess!), and in most countries, only the military is allowed to boost radio transmissions above a very specific level. How high this is, will depend entirely on your local authorities.
They can of course be daisy chained, as you put it, its simply a case of one station receiving a signal and relaying it (routing it) to the correct station, but we really are talking proper line of site stuff here, a small mountain in the way and boom, your radio waves are absorbed and the signal is lost.
Personally I don't know any commercial infrastructures you could "hire" out for this purpose in the UK, even "hotspots" are very localised to cover specific busy areas, very much like a building is WiFi enabled i.e. repeaters placed in most rooms all wired together using ethernet. However, whether that is the case where you are, then I don't know!
EDIT: Also, just to re-iterate the above is totally true. Mobile phones have a small patch aerial in them usually, giving them a roughly 60degree "conical" range emanating from the back of the device (some will have small omni's i guess, but the range will still be 100 meters at very best) To get an idea, just get hold of an off the shelf 10dB omni aerial to see the size (think WW2 walkie talkie aerial). So while the device would be able to receive assuming your infrastructure, it wouldn't be able to send back, and unfortunately most communication protocols these days are of the guaranteed service type, even UDP wouldn't help as your device wouldn't even be able to handshake in amongst all its lost packets.
To give you an idea, I have managed to get a remote control vehicle to receive VERY patchy WiFi from a powerful 1W boosted mahoosive aerial (on military ground I should add... so it was legal) up to about 1km away with a 10dB omni aerial attached to it. And even then i struggled to get enough throughput to receive 100kb images every 10 seconds...