Will this affect using his shops stock on the website ? And how much share should I demand ?
You'd transfer stock as it was required for orders, probably set a price at cost or slightly above. Shop would invoice web firm and web firm would pay shop on set terms (time wise).
How would OCuk deal with a % for me, if this was the situation for you?This is also @ Ruper Lowery
Rupert left ocuk several years ago, why not ask Spie as he owns it

I doubt very much if ocuk would want to enter into such an arrangment - I imagine it's only being considered in this case as it's highly speculative and he doesn't want to risk any investment in it.
The percentage he offers and terms for stock / resources will be up to the two of you to negotiate, there really is no set rate he should offer.