The extra 6 pin cables for the graphics card should be in the box somewhere. Make sure to plug them into the right ports on the PSU, which will be explained in the PSU manual.
The DVD/CD drive needs a SATA data lead from the drive to the motherboard, and a power lead from the PSU.
Glad to see you've got it working (sort of). As per previous advice, try the two cards individually, and if both are OK, make sure Crossfire is ticked in the Catalyst Control Centre. Connect the cards up using 6 pin cables only, and forget about molex to 6 pin entirely.