DRUM ROLL PLEASE......
Installed the Sapphire 5850 Xtreme easily, the hardest part was the cable management afterwards. The setup is exactly like the diagram above.
First off some single 5850 benchmarks:
And now some 5850 Crossfire benchmarks:
The biggest gain was over doubling my Unigine Heaven score

Also the massive boost in Dirt 3 is impressive. My 3Dmark11 went from P3597 to P6205, I never imagined it would go up that much!
The AvP benchmark kept exiting to Desktop in Crossfire so I dont have a result for that, but Im sure it would have been an improvement. The funny thing is, Bad Company 2 went from averaging around 65fps to 80fps, I was kinda hoping to be playing in the 90s (although it does change through gameplay anything from 75fps to 110fps!).
As for temperature, on load both cards hover around the 51C mark with their fans running at 40% so I've got room for overclocking (not that I need to lol). Overall I'm very happy with the upgrade and can't wait for Battlefield 3 (my new Unigine Heven score gives me confidence I'll be able to play BF3 maxed out at 1650*1050 at over 60fps)
Thanks to everyone for their advice

and Overclockers for their brilliant service
P.S. Will test power usage under load and idle and report back