Assuming a game/driver set with no massive problems, you'd be hard pressed to notice much of a difference between any 670/680/7950/7970 sli/xfire setup or the 7990/690. If in a game you're talking about 10% difference covering them all, and that 10% is 120-132fps, its not very noticeable.
Because of cpu limits and higher framerates you're likely to be more frequently limited by maximums. On a single card you might have a 670 giving you a 60fps max, and a 7970 giving you 75fps, but in xfire/sli, its 115fps vs 120fps, because while the 7970 is faster, at that fps cpu is becoming more of a factor and lowering the difference.
Meh, in most situations 10% more performance just isn't very noticeable most of the time.
The 4870x2 was an AWESOME card, because 4870 1gb cards weren't even out yet, and the 512gb cards were something like £180, a 4870x2 had 1gb per core and was only £330, it was cheaper with more memory. It was actually faster, better at high res and cheaper than buying two separate cards. Since then, dual gpu cards have costed more, been more clock speed limited(because of power limitations), and been out seriously late, well after you can just buy two single cards.
The 4870x2 was out weeks after the 4870, and before the higher memory version, a 7990, is a joke, you could have had 2x7970 what 8 months before the first unoffical 7990's, well over a year before the official 7990's, cheaper, and faster.
Old dual gpu cards had several reasons to buy them and the only downside was marginally reduced performance vs 2 separate cards with same memory amount, since then, there is no upside at all to dual gpu cards. Higher failure rate, higher cost, louder, bigger/longer/fit in less cases, slower, and massive long wait to get a level of performance you can achieve for a lower cost 6months + earlier, I would also say single gpu cards have a huge interest in second hand market after new gen cards are out, very few people want to pay heavily for a now matched card that uses twice the power.